Cold stabilisation now
Cold stabilisation of wine is one of those things that is very difficult to determine. When is a wine stable, and under which circumstances is it stable? The method used to determine the level of cold stabilisation will determine that. At one time the water bath method using electrical conductivity as a measure was popular, but it actually only determined the level of cold stabilisation at 0°C. The minus four degrees centigrade freezer test, determined the level of stability that the wine will have under those circumstances, and not necessarily for a longer time, and at a lower temperature.
With all these philosophical headaches to contend with, the only proper way of stabilisation was to keep the wine cold for a very long time, or to seed it with crystals at a very low temperature. The effect was that the wine was often exposed to oxygen at very low temperatures where it can dissolve very easily, but it would only react at higher temperatures. Apart from these negatives the energy usage, cost, lowered total acidity and loss of carbon dioxide gas was a worry. Often wine had to be sparged with nitrogen inline after stabilisation to push out oxygen, while removing CO2, possibly flavour, and the nitrogen itself dissolving at low temperatures, foaming when the wine is mixed at a higher temperature. The biggest drawback in future will be the energy used during this process. After this long list of negatives, one would think that there would have been alternatives by now. Well there are, sort of.
Being an avant garde winemaker in my youth, I dabbled with mannoproteins even before they hit the shelves. Here was a product that would keep all the valuable attributes of the wine, without any of the negatives of cold stabilisation. The only drawback was that it only worked so-so. The product was too dodgy to use on big Tesco orders, and the amount of comebacks was always just below the threshold for concern, but only just. At bottling time I would often find that the mannoproteins would form a slimy layer on the filter sheets, and sometimes even block a filter. This meant that some of the proteins where being filtered out. I tried to compensate for this by adding the mannoproteins during bulk filtration, thereby filtering and dosing it at the same time, but I never knew whether the difference was just in my head. All said, Australia shunned the product until other countries stopped experimenting with it.
Another alternative for stabilisation is electrodialysis. This procedure involves a membrane that, at room temperature, removes destabilizing ions, potassium, calcium, tartrate salts using quite a low current. The energy usage is very low, but the capital requirement is quite high. Many people are touting this technology as the next big thing, because it does not seem to lower the TA significantly, and also (apparently) seems to improve the sensory aspects of wine.
The latest technology that is making my tail wag is the use of CMC. CMC is carboxymethylcellulose, and it was recently legalised by the OIV. CMC is used in food as a viscosity modifier and emulsion stabilizer. CMC works the same way as mannoproteins inhibiting crystal growth, and is added to wine just before bottling. The only negative aspect of CMC is that it is not a natural product, and if not used, has a relatively short shelf-life. The OIV specified that CMC’s used for winemaking must be of wood origin, so that would help a bit for the conscience.
I hope CMC is what it is cooked up to be, because it could be a wonderful breakthrough.
Tags: winemaking
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7 Responses to “Cold stabilisation now”Leave a Reply |
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August 26th, 2010 at 4:40 pm
CMC has been around for a little while now, but the biggest headache we’ll all surely face in the very near future is increased pressure to omit all things ‘unnatural’. There are new products creeping onto the market along the lines of mannoprotein stabilisation; more specifically MP40 released by yeast as the degrade. I believe the research centred around the wines of Burgundy, which seemed naturally stable in terms of tartrates after having received prolonged lees contact.
Yes, there seem to be some practical issues concerning adding to the wines at the correct temperature, and filtering at the correct temperature to maintain efficacy. However, the fact that it is a natural by-product of wine yeast surely means that we should be focussing more on this type of product? I will be trialling some next year; implications for traditional method sparkling wines are also quite exciting.
August 27th, 2010 at 8:59 am
Beste Louis
Jy het alles mooi saam gevat.
Het jy al met CMC gewerk, wat is jou ervaring tot dusver?
Behalwe dat die produk nie toegelaat is vir organiese wyne nie, wonder ek net wat se invloed het dit op die mens?
Ek sal ook graag wil weet of dit effektief sal wees op wyne met hoe % Kalium, wat so dikwels in ons warmer streke voorkom?
August 28th, 2010 at 6:36 am
I agree with James Lambert regarding the move towards natural products, being regarded as more favourable, and it is my feeling too. If Mannoproteins worked I would have been using them, but the fact is that they only work so well, and not better, in my experience. I got away with using mannoproteins for many years, without huge incident, and other people can try their luck if they want.
Burgundy is Burgundy, ie it is cold, even during harvest time and you would have a huge degree of natural cold stabilisation of the wine due to cold temperatures. The french were some of the first to adopt the use of mannoproteins, and some of the new world flying winemakers who passed through these old wine countries were the first to write about mannoproteins. The Australians wouldn’t touch the stuff, because it didn’t work, in their environment. In Burgundy they don’t add acid, they normally don’t need to, so it is difficult to compare the tartrate stability of burgundian wines to South African wines. All wines don’t have the luxury of going through a winter on lees.
I have personally not used CMC, but I would I have heard good reports. I cannot report on isolated instances that the product worked, and try to generalise, because it might simply be unrepresentitive of the industry. Time will tell.
If you are looking for CMC, I know where you can score some my bru, but I cannot vouch for its effectiveness.
September 6th, 2010 at 8:08 pm
I have since learned that CMC is not advised to be used to stabilise red and rosé wine, because it might precipitate colour.
September 14th, 2010 at 4:13 pm
I heard too that CMC should be tested before addition to check also the colloids interaction and it is true that CMC could not be used in red and rosé wine.
Anyway I would be really interested to know the Tesco threshold for concern. I have good feedbacks with the mannoprotein Claristar of Oenobrands from Europe and also from US. The thing is that the stabilization is done instantaneously once the product is in the wine vs. 5-7 days before bottling for CMC.
September 16th, 2010 at 4:46 pm
I’ve just started lab trials with cmc. So far I’m really impressed. We only cold stabilise whites and it seems to do it well without the power associated with the more traditional methods. Plus it works in 24 hours! Just get your wine ready and add away a few days prior to bottling. No we just have to wait till the product gets rubber stamped in Australia
October 6th, 2011 at 12:01 pm
Please note that CMC comes from wood and is transformed to let the cellulose be soluble in the wines.
Its carbon footprint is very low. Much lower that cold stabilisation, electrodialysis. Much safer than mannoproteins. Much better for the environment to produce that metatartaric acid and has longer efficiency than the latter.
Shelf life is much longer that you could imagine (we have wine stabilized since 2003 with CMC, without any problem).
Just one thing in addition NEVER ADD IT JUST BEFORE BOTTLING. For still wines add it at least three weeks before filtration and bottling. For sparkling wines add it during the tirage.
For rosé and red wine check the efficiency before using, let the trial at -4°C for one or two weeks. No more impact on the colour than cold stabilisation.